Dielectric constant of advanced ceramics

The dielectric constant, also known as the relative permittivity (εr), is a measure of a material's ability to store electrical energy in an electric field. It represents the ratio of the material's dielectric constant to the vacuum dielectric constant (ε₀). The higher the dielectric constant, the greater the ability to store charge, which is critical in capacitors, insulators, and high-frequency electronic components.

Advanced ceramic materials are widely used in high-frequency, high-power, microwave, radar and packaging applications due to their different dielectric properties. When selecting materials, companies should consider factors such as operating frequency, thermal management, mechanical structure and dimensional accuracy to evaluate the best material combination.

dielectric constant

The importance of dielectric constant in ceramics

Ceramic materials are widely used in electronics and electrical insulation because of their:

  • High dielectric strength
  • Stable thermal and electrical properties
  • Low dielectric loss
  • Resistance to corrosion and environmental degradation

Dielectric constant plays a critical role in RF components, substrates, capacitors, antennas and semiconductor packages. Selecting the right ceramic material with the right dielectric constant ensures optimum performance, especially in high frequency and high temperature environments.

Factors affecting the dielectric constant of ceramics

  • Crystal structure: materials with polar structures usually exhibit higher εr.
  • Temperature: Depending on the type of material, the dielectric constant increases or decreases with temperature.
  • Frequency: at high frequencies, εr usually decreases due to diminished dipole polarization.
  • Porosity: the higher the porosity, the lower the εr (εr ≈ 1) due to the presence of air.
  • Grain size and density: Finer grains and higher densities generally improve εr consistency.

Dielectric loss and frequency stability

εr determines the charge storage capacity, while the dielectric loss (tan δ) measures the energy dissipation. materials such as PTFE or h-BN have a very low tan δ, making them well suited for high-frequency RF designs.

Another factor is frequency dependence. Some ceramics (e.g., zirconia) have high dielectric constants but exhibit greater loss and instability in the GHz range, while AlN and Si₃N₄ remain more stable.

Dielectric Constants of Common Ceramic Materials

Ceramic materials Dielectric constant (εr) hallmark
Aluminum oxide (Al₂O₃) 9-10 Low loss, structurally stable, cost-effective
Zirconium oxide (ZrO₂)  18-25 High strength, high thermal expansion
ZTA20 (zirconia toughened alumina) 12-15 Combined strength and dielectric properties
Silicon Nitride (Si₃N₄) 7-8 High strength, low dielectric loss
Aluminum Nitride (AlN)  8.5-9 High thermal conductivity, low dielectric loss
Silicon Carbide (SiC)  9.7-10.2 Excellent high frequency stability
Beryllium oxide (BeO) 6.5-7.5 High thermal conductivity, low εr
Hexagonal boron nitride (h-BN) ~4 Very low εr, excellent thermal stability
MGC (machinable glass-ceramics) 5.6 CNC machinable, ideal for microwave structures

*Data is for reference only.

Material Selection Guide: Selecting Ceramics Based on Dielectric Constant

application direction recommendation material rationale
High Frequency/Low Loss Aluminum Nitride, Beryllium Oxide, Hexagonal Boron Nitride Low εr + low loss + high thermal conductivity
Power Packaging/Cooling Aluminum Nitride, Aluminum Oxide Moderate εr + excellent heat dissipation
Radome/radome MGC, BeO Good processability + low εr
high frequency capacitor Zirconium oxide (ZrO₂) High εr + good mechanical strength
microwave structure Magna Easy processing + stable dielectric properties

Need help choosing the right ceramic?

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Dielectric constant: ceramics and other materials

To help you understand the advantages of ceramic dielectric constants for material selection, the table below compares ceramic materials with common insulator materials, materials for the electronics industry and polymer plastics:

Ceramic
Plastic
Insulation Fluid/Air

*Data is for reference only.

Applications based on ceramic dielectric constant

  • Applications: RF antennas, power amplifier substrates, filters
  • Key Benefits: AlN has a medium dielectric constant (~9) and ultra-high thermal conductivity (170-200 W/m-K), which reduces signal delay and heat buildup.
  • Case study: A 5G base station supplier used AlN instead of aluminum oxide substrates to improve the thermal management of the amplifier by 30% and significantly improve signal stability.
  • Applications: satellite radar systems, microwave resonators, antenna windows
  • Key Benefits: BeO has a low εr (6.5-7.5) and very high thermal conductivity (330 W/m-K) to minimize microwave signal loss and increase transmission rates.
  • Case Study: A satellite manufacturer uses BeO as a microwave window, reducing its size by 20% compared to quartz while improving signal sensitivity.
  • Applications: IC packages, power modules, LED substrates
  • Key Benefits: Alumina has good insulating properties (dielectric strength >15 kV / mm) and a stable dielectric constant (~9.8), making it suitable for high-density packaging.
  • Case Study: A Power Semiconductor Company Uses 96% Alumina Ceramic Substrates in MOSFET Modules to Improve Insulation and Maintain Excellent Thermal Conductivity.
  • Applications: radar structures, microwave photonic devices, signal couplers
  • Key benefits: stable εr (~5.6), easily machined by CNC, suitable for complex RF/microwave designs.
  • Case Study: A defense communications company uses MGC for microwave feed structures. Processing time was reduced by 30% and dimensional consistency was improved compared to quartz.
  • Applications: high voltage capacitors, plasma equipment, impedance matchers
  • Key benefits: High dielectric constant (18-25), ideal for applications requiring high energy density.
  • Case Study: A plasma equipment manufacturer uses ZrO₂ as a dielectric layer for plasma field capacitors, allowing for a more compact design with the same energy storage.

Popular advanced ceramic materials

Frequently Asked Questions (FAQ)

Due to their varying crystal structures, densities and electronic structures, some materials are designed for high εr, while others prioritize insulation.

Not necessarily. For high-frequency or high-speed applications, low εr and low-loss angular tangent are usually preferable.

Aluminum nitride (AlN) and beryllium oxide (BeO) both have excellent thermal conductivities and moderate εr.

Commonly used methods include:

  • resonant cavity method

  • Impedance analysis

  • Measurement of capacitance by means of a parallel plate device

Typically, values between 4 and 10 are suitable for high frequency substrates, while higher values (>20) are used for capacitors .

Zirconia and barium titanate (not included in the chart) have very high dielectric constants, the latter exceeding 1000 .

Ceramics are more stable to temperature, have better aging resistance and higher thermal conductivity, making them ideal for harsh environments.

Alumina ceramics have a dielectric constant of about 9-10, making them versatile and widely used in electronic products.