About Zirconia Ceramics (ZrO)2)

Zirconia generally refers to zirconium dioxide, with the chemical formula ZrO2It is the main oxide of zirconium, which is white, odorless and tasteless crystal under normal condition, and is difficult to dissolve in water, hydrochloric acid and dilute sulfuric acid.

Unlike conventional ceramics, which tend to harden and become brittle, zirconia has a high degree of strength, wear resistance and flexibility that far exceeds that of most other technical ceramics. Zirconia is a very strong industrial ceramic with excellent properties in terms of hardness, fracture toughness and corrosion resistance, which is why it is sometimes referred to as “ceramic steel”.

Zirconia is available in several common grades, the most common being yttrium oxide partially stabilized zirconia (Y-PSZ) and magnesium oxide partially stabilized zirconia (Mg-PSZ). Its unique resistance to crack propagation and high thermal expansion make it an excellent material for joining ceramics to metals such as steel.

Density of zirconia ceramics:

The theoretical density of pure zirconia is 5.89g/cm³, but pure zirconia ceramics are prone to cracking at about 1100℃. Therefore zirconia ceramics need to add yttrium oxide as a stabilizer to achieve stability at room temperature, so yttrium oxide partially stabilized zirconia ceramics have a density of 6.05g/cm³.

Hardness of zirconia ceramics:

Zirconia ceramics are a very strong, advanced ceramic with a Vickers hardness of 1250, and its fracture toughness is so good that it can be used to make a wide variety of knives and ceramic parts.

Zirconia structural ceramics.

Performance Characteristics of Zirconia Ceramics

Advantages and disadvantages of zirconia ceramics

  • High bending strength and hardness

  • Good friction properties.;

  • Electrical insulators.;

  • Acid and alkali corrosion resistance.;

  • Modulus of elasticity similar to steel.;

  • The coefficient of thermal expansion is similar to that of iron.

Mechanical Properties of Zirconia Ceramics

sports event unit (of measure) Zirconia Ceramics Magnesium partially stabilized zirconia ZTA
color -- fig. reactionary yellow (color) fig. reactionary
intensity g/cm³ 6.05 5.7 4.1~4.38
durometer GPa 12.5 11.8 15
compressive strength MPa 2100 1750 2350
bending strength MPa 850 900 700
Fracture toughness MPa・m1/2 4~5 >7.0 3.5
Young's modulus GPa 200 200 310
Poisson's ratio -- 0.30 0.30 0.26

Thermal Properties of Zirconia Ceramics

sports event unit (of measure) Zirconia Ceramics Magnesium partially stabilized zirconia ZTA
Maximum operating temperature ℃(without mechanical load) 1000 1000 1500
Thermal conductivity@25℃ W/(m・K) 2 2.2 20
Coefficient of linear thermal expansion 40 - 400°C, x 10-6/C 10  10.2  8
specific heat J/(kg・K) 460 400 720
thermal shock resistance ℃ (into water) 300 350 300

Electrical Characteristics of Zirconia Ceramics

sports event unit (of measure) Zirconia Ceramics Magnesium partially stabilized zirconia ZTA
dielectric constant 1MHz 30 28 10.2
Dielectric strength (6.35mm) ac-kV/mm 9.0  9.4  9.0
dielectric loss 1MHz 16 x 10-4 10 x 10-4 20 x 10-4
Volume Resistance@25℃ Ω・cm >1013 >1012 >1014
Volume Resistance@500℃ Ω・cm >103  >103 >104

Note: All the above parameters are typical values for zirconia ceramics and may vary from batch to batch.

What are the uses of zirconia ceramics?

  • Wire forming/drawing dies;
  • Insulated rings for thermal processes;
  • Precision shafts in high wear environments;
  • Furnace treatment tubes;
  • Abrasion-resistant pads;
  • Thermocouple protection tubes;
  • Sandblasting nozzles;
  • Refractory materials;
  • Extrusion molds;
  • Bushings and covers;
  • Kiln furniture crucibles;
  • Fiber optic ferrule and sleeve;
  • Knives and blades;
  • Fuel cell parts;
  • Bearings and rollers;
  • Weld nozzles and pins;
  • Laser parts;
  • Gas igniter;
  • Electrical insulators;
  • Ceramic guides;
  • Oxygen Sensor;
  • Medical and surgical components;
  • Mechanical seals;
  • Pumps, pistons and cylinder liners.

Domestic Zirconia Manufacturers

Zhihao Ceramics is a professional zirconia ceramics manufacturer and processor in China. Since 2013, we have participated in and supplied more than 3,000 kinds of precision ceramic products to hundreds of companies.
We can provide you with ceramic machining, ceramic materials, ceramic casting, ceramic metal encapsulation and surface metallization services, and are committed to providing products and services that meet or exceed our customers' quality requirements.

Zirconia Ceramics Processing

To Good Ceramics is your zirconia ceramics custom fabrication specialist for your advanced ceramics prototyping needs. We are always happy to utilize our years of experience in advanced ceramics to advise on materials, designs and applications. If you are looking to purchase aluminum oxide plates, rods, tubes, or custom machined parts, please contact us and each of our experts will be happy to assist you.

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